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Sr(Cr0.2Mn0.2Fe0.2Co0.2Ni0.2)O3: A novel high-entropy perovskite oxide with enhanced electromagnetic wave absorption properties
Journal of Materiomics ( IF 9.4 ) Pub Date : 2023-12-23 , DOI: 10.1016/j.jmat.2023.11.019
Mengru Li , Qing Zhi , Jinlu Li , Chengwen Wu , Xuewen Jiang , Zhiyu Min , Rui Zhang , Hailong Wang , Haibin Wang , Bingbing Fan

Perovskite materials (ABO3) possess a wealth of elements selectable and exhibit a diverse range of octahedral transformations. The emergence of high-entropy perovskite ceramics provides a fresh perspective for advancing the field of wave-absorbing materials. In this study, we concentrate on the wet chemical synthesis of a high-entropy perovskite oxide, Sr(Cr0.2Mn0.2Fe0.2Co0.2Ni0.2)O3, and investigate its crystal structure, microstructure, chemical composition, magnetic properties, and microwave absorbing capabilities. The results indicate that when sintered at a temperature of 1350 °C, the sample achieves a minimum reflection loss of −54.0 dB at a frequency of 9.68 GHz, accompanied by a maximum effective absorption bandwidth (EAB) of 7.44 GHz at the thickness of 1.8 mm. The high-entropy design of the B-site induces distortions of oxygen vacancy and octahedral structure of the perovskite material. This leads to the fine tuning of its dielectric and magnetic properties, thereby endowing perovskite with excellent electromagnetic wave absorption capabilities. Consequently, perovskite emerges as a promising new electromagnetic wave absorption material with significant potential.



中文翻译:

Sr(Cr0.2Mn0.2Fe0.2Co0.2Ni0.2)O3:一种具有增强电磁波吸收性能的新型高熵钙钛矿氧化物

钙钛矿材料(ABO 3)具有丰富的可选择元素,并表现出多种八面体转变。高熵钙钛矿陶瓷的出现为吸波材料领域的发展提供了全新的视角。在本研究中,我们专注于湿化学合成高熵钙钛矿氧化物Sr(Cr 0.2 Mn 0.2 Fe 0.2 Co 0.2 Ni 0.2 )O 3,并研究其晶体结构、显微结构、化学成分、磁性能和性能。微波吸收能力。结果表明,在 1350 °C 温度下烧结时,样品在 9.68 GHz 频率下实现了 -54.0 dB 的最小反射损耗,同时在 1.8 厚度下实现了 7.44 GHz 的最大有效吸收带宽(EAB)。毫米。B位的高熵设计导致了钙钛矿材料的氧空位和八面体结构的扭曲。这导致其介电和磁性的微调,从而赋予钙钛矿优异的电磁波吸收能力。因此,钙钛矿成为一种有前途的新型电磁波吸收材料,具有巨大的潜力。

更新日期:2023-12-23
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