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Enhanced oxidation potential of holes under visible light for organic photo-oxidation
Chem ( IF 23.5 ) Pub Date : 2024-03-27 , DOI: 10.1016/j.chempr.2024.03.018 Jiaqi Zhao , Li-Zhu Wu , Tierui Zhang
中文翻译:
可见光下空穴氧化电位增强,用于有机光氧化
更新日期:2024-03-27
Chem ( IF 23.5 ) Pub Date : 2024-03-27 , DOI: 10.1016/j.chempr.2024.03.018 Jiaqi Zhao , Li-Zhu Wu , Tierui Zhang
The balance between oxidation potential and spectral response range is a critical consideration in photocatalysis. In this issue of Chem, Zhu and co-workers present a general approach in which Fe3+ additives initiate the generation of intra-valence band holes in organic conjugated molecular crystals under visible-light irradiation. This approach significantly enhances the oxidation potential for photocatalytic pollutant degradation.
中文翻译:
可见光下空穴氧化电位增强,用于有机光氧化
氧化电位和光谱响应范围之间的平衡是光催化中的关键考虑因素。在本期《Chem》中,Zhu 及其同事提出了一种通用方法,其中 Fe 3+添加剂在可见光照射下引发有机共轭分子晶体中价内带孔的产生。这种方法显着增强了光催化污染物降解的氧化潜力。