Aluminum is the most abundant metal in the earth’s crust at 8%, and it is also widely available domestically in many countries worldwide, which ensures a stable supply chain. To further the applications of aluminum (Al), such as in catalysis and electronic and energy storage materials, there has been significant interest in the synthesis and characterization of new Al coordination compounds that can support electron transfer (ET) and proton transfer (PT) chemistry. This has been achieved using redox and chemically noninnocent ligands (NILs) combined with the highly stable M(III) oxidation state of Al and in some cases the heavier group 13 ions, Ga and In.

中文翻译：

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用非无害配体扩大铝化学的范围

铝是地壳中含量最丰富的金属，含量为8%，而且在全球许多国家国内也广泛供应，这确保了稳定的供应链。为了进一步促进铝 (Al) 的应用，例如在催化、电子和储能材料中的应用，人们对能够支持电子转移 (ET) 和质子转移 (PT) 的新型铝配位化合物的合成和表征产生了浓厚的兴趣。化学。这是通过使用氧化还原和化学非无害配体 (NIL) 与 Al 的高度稳定的 M(III) 氧化态以及在某些情况下较重的第 13 族离子 Ga 和 In 相结合来实现的。