A simple and general approach for the synthesis of ketones via a metal-free denitrogenative alkylation of vinyl azides with redox-active esters or Katritzky salts under visible light irradiation is described herein. This method features a broad substrate scope and good functional group compatibility including valuable transformation of bioactive molecules, thereby providing a sustainable and alternative technique for ketone preparation compared to the present strategies.

中文翻译：

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乙烯基叠氮化物与烷基自由基的无金属光诱导脱氮烷基化反应生成酮

本文描述了在可见光照射下通过乙烯基叠氮化物与氧化还原活性酯或卡特里茨基盐的无金属脱氮烷基化来合成酮的简单且通用的方法。该方法具有广泛的底物范围和良好的官能团相容性，包括有价值的生物活性分子转化，从而与现有策略相比，为酮制备提供了一种可持续的替代技术。