Electrochemistry-driven techniques for advanced energy storage/conversion and environmental protection play a crucial role in achieving sustainable development goals. As an indispensable component in diverse electrochemical systems, electroactive materials gain soaring interest in terms of rational design and sustainable synthesis. Notably, mechanochemistry-based green and powerful synthesis has been widely employed to fabricate diverse electroactive materials, given their scalability and tunability. Recently, mechanochemically synthesized electroactive materials have been widely applied in various environmental and energy fields, leading to significant progress. However, a systematic analysis of these advancements is still missing. Herein, we comprehensively discuss recent achievements in mechanosynthesized electroactive materials for sustainable energy and environmental applications. The development of mechanochemical synthesis is introduced, along with different types of mechanosynthesized electroactive materials. Subsequently, the review delves into the applications of these materials in advanced energy conversion/storage systems and environmental remediation. The rational design of electroactive materials and their structure-performance correlation are illustrated by discussing the effects of the mechanochemical process on the internal and external properties of materials and their electrochemical performance. Lastly, key perspectives in this field are discussed, including mechanochemical process monitoring, field-assisted mechanochemical synthesis, material performance optimization, practical applications, and mechanochemistry-driven fuels/chemicals synthesis. By illustrating current advances and perspectives related to the development of mechanosynthesized electroactive materials, this review aims to shed some light on upcoming research on green mechanochemical synthesis-driven energy and environmental sustainability.

中文翻译：

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用于可持续能源和环境应用的机械合成电活性材料：批判性评论


用于先进能量存储/转换和环境保护的电化学驱动技术在实现可持续发展目标中发挥着至关重要的作用。作为各种电化学系统中不可或缺的组成部分，电活性材料在合理设计和可持续合成方面引起了越来越多的兴趣。值得注意的是，由于其可扩展性和可调节性，基于机械化学的绿色和强大的合成已被广泛用于制造各种电活性材料。近年来，机械化学合成的电活性材料已广泛应用于各种环境和能源领域，并取得了重大进展。然而，仍然缺乏对这些进步的系统分析。在这里，我们全面讨论机械合成电活性材料在可持续能源和环境应用方面的最新成就。介绍了机械化学合成的发展以及不同类型的机械合成电活性材料。随后，综述深入研究了这些材料在先进能源转换/存储系统和环境修复中的应用。通过讨论力化学过程对材料内外性能及其电化学性能的影响，阐明电活性材料的合理设计及其结构与性能的相关性。最后，讨论了该领域的关键观点，包括机械化学过程监测、现场辅助机械化学合成、材料性能优化、实际应用和机械化学驱动的燃料/化学品合成。 通过阐述与机械合成电活性材料发展相关的当前进展和前景，本综述旨在为即将到来的绿色机械化学合成驱动的能源和环境可持续性研究提供一些启示。