This review article discusses the challenges of particle assembly and proposes coassembly of synthetic particles with heterogeneous assembling components as a promising solution. Particle assembly using particles as building blocks offers access to superstructural and highly functional materials. However, the rigidity and preorganized structures of particles limit their ability to contact and fuse, making particle self-assembly kinetically and/or thermodynamically unfavorable. Co-assembly of synthetic particles with synthetic/bioderived macromolecules and/or particles bearing complementary surficial chemistries provides efficient pathways to overcome these barriers, enabling the attainment of regular superstructural and highly functional materials. The review focuses on strategies and future perspectives for coassembly of synthetic particles with heterogeneous assembly components, which include block copolymers, DNA, proteins, and particles bearing different surficial chemistries. Co-assembly systems and their potential applications are reviewed. The article also discusses the challenges and future needs in the field of coassembly of synthetic nanoparticles with heterogeneous assembly components.

中文翻译：

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合成颗粒与异质组分的共组装

这篇综述文章讨论了粒子组装的挑战，并提出将合成粒子与异质组装组件共组装作为一种有前途的解决方案。使用粒子作为构建块的粒子组装提供了获得上层结构和高功能材料的途径。然而，颗粒的刚性和预组织结构限制了它们接触和融合的能力，使得颗粒自组装在动力学和/或热力学上不利。合成颗粒与合成/生物衍生大分子和/或具有互补表面化学性质的颗粒的共组装提供了克服这些障碍的有效途径，从而能够获得常规的超结构和高功能材料。该综述重点关注合成颗粒与异质组装成分共组装的策略和未来前景，其中包括嵌段共聚物、DNA、蛋白质和具有不同表面化学性质的颗粒。审查了共组装系统及其潜在应用。本文还讨论了合成纳米颗粒与异质组装组件共组装领域的挑战和未来需求。