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Perovskite Colloidal Quantum Dots with Tailored Properties: Synthesis Strategies and Photovoltaic Applications
ACS Energy Letters ( IF 22.0 ) Pub Date : 2024-05-09 , DOI: 10.1021/acsenergylett.4c00632
Dayeong Choi 1 , Hangyeol Kim 1 , Yurim Bae 1 , Seyeong Lim 1 , Taiho Park 1
Affiliation  

Perovskite colloidal quantum dots (Pe-CQDs) are promising materials for the next-generation optoelectronic devices due to their outstanding material properties derived from perovskites and QDs. Among the various synthesis methods, the hot injection (HI) method has been mainly used to fabricate the active layer of photovoltaics. For the effective application of Pe-CQDs, the synthesis variables that determine the properties of Pe-CQDs should be determined. The variables of Pe-CQDs synthesis can be divided into two types. First, the crystal nucleation and growth rates can be physically modified by reaction time and temperature. Second, the synthesis mechanism can be chemically modified by adjusting the precursors and injection type. In this review, various HI-based strategies are systematically classified and investigated. Furthermore, we discuss on how Pe-CQDs with enhanced properties prepared by advanced synthesis strategies affect the power conversion efficiency and stability of photovoltaics. Finally, the current limitations of Pe-CQD synthesis and future agendas are presented.

中文翻译:

具有定制特性的钙钛矿胶体量子点:合成策略和光伏应用

钙钛矿胶体量子点(Pe-CQD)因其源自钙钛矿和量子点的出色材料特性而成为下一代光电器件的有前途的材料。在各种合成方法中,热注入(HI)法主要用于制造光伏电池的有源层。为了有效应用 Pe-CQD,应确定决定 Pe-CQD 性能的合成变量。 Pe-CQDs合成的变量可分为两类。首先,晶体成核和生长速率可以通过反应时间和温度进行物理改变。其次,可以通过调整前驱体和注射类型来对合成机理进行化学修饰。在这篇综述中,对各种基于 HI 的策略进行了系统的分类和研究。此外,我们还讨论了通过先进合成策略制备的具有增强性能的Pe-CQD如何影响光伏发电的功率转换效率和稳定性。最后,提出了 Pe-CQD 合成的当前局限性和未来议程。
更新日期:2024-05-10
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