当前位置: X-MOL 学术Radiat. Phys. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Sustainable and fast synthesis of zinc-phthalocyanine for gamma radiation dosimeter application
Radiation Physics and Chemistry ( IF 2.9 ) Pub Date : 2024-05-08 , DOI: 10.1016/j.radphyschem.2024.111816
Bojana R. Vasiljević , Daliborka Odobaša , Ivica Vujičić , Milica Budimir Filimonović , Krisjanis Smits , Dušan Mijin , Dragana Marinković

In the present research, the two different systems of dye based on zinc phthalocyanine were prepared by microwave-induced synthesis and conventional methods. They were evaluated as new effective chemical-based dosimeters for gamma irradiation. The sensitivity of the prepared dosimeters was examined by studying the comparative results between them through the changes in structural and optical properties upon exposure to different gamma irradiation doses. The color bleaching of the solutions was followed spectrophotometrically. Gradual changes from blue to light yellow color of zinc phthalocyanine solution, with the increase of the gamma radiation dose, were observed due to the decomposition of the dyes based on the zinc phthalocyanine. The synthesized zinc phthalocyanine chemical-based dosimeters for measurement of gamma irradiation up to 25kGy showed excellent stability after irradiation in terms of morphology and structure, which makes them a suitable novel material as composite-based dosimeters of gamma irradiation.

中文翻译:

可持续快速合成锌酞菁用于伽马辐射剂量计应用

在本研究中,通过微波诱导合成和常规方法制备了两种不同的基于锌酞菁的染料体系。它们被评估为新型有效的基于化学的伽马射线剂量计。通过研究不同伽马辐照剂量下结构和光学性能变化的比较结果,检查了所制备的剂量计的灵敏度。通过分光光度法跟踪溶液的颜色漂白。随着γ辐射剂量的增加,观察到由于基于锌酞菁的染料的分解,锌酞菁溶液的颜色逐渐从蓝色变为浅黄色。合成的锌酞菁化学剂量计可用于测量高达25kGy的伽马辐照,辐照后在形态和结构方面表现出优异的稳定性,这使得它们成为适合作为复合基伽马辐照剂量计的新型材料。
更新日期:2024-05-08
down
wechat
bug