This review summarizes the latest discoveries in the field of C−H activation by copper monoxygenases and more particularly by their bioinspired systems. This work first describes recent background on copper-containing enzymes along with additional interpretations about the nature of the active copper-oxygen intermediates. It then focuses on relevant examples of bioinorganic synthetic copper-oxygen intermediates according to their nuclearity (mono to polynuclear). This includes a detailed description of the spectroscopic features of these adducts as well as their reactivity towards the oxidation of recalcitrant C_sp³-H bonds. The last part is devoted to the significant expansion of heterogeneous catalytic systems based on copper-oxygen cores (i.e. within zeolites frameworks).

中文翻译：

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铜氧加合物：C−H 活化表征和性能的新趋势

这篇综述总结了铜单加氧酶尤其是其仿生系统在 C−H 激活领域的最新发现。这项工作首先描述了含铜酶的最新背景以及对活性铜氧中间体性质的额外解释。然后根据其核性（单核到多核）重点介绍生物无机合成铜氧中间体的相关示例。这包括这些加合物的光谱特征及其对顽固的 C _{sp ³} -H 键氧化的反应性的详细描述。最后一部分致力于基于铜氧核（即在沸石框架内）的多相催化系统的显着扩展。