当前位置: X-MOL 学术Dalton Trans. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
An elastic single crystal composed of one-dimensional chiral coordination polymers
Dalton Transactions ( IF 4 ) Pub Date : 2024-05-13 , DOI: 10.1039/d4dt01050g
Yan Zhang 1 , Yu-Xia Li 1 , Kai-Ge Gao 2 , Jia-Hui Zhang 1 , Jie-Sheng Hu 1 , Jun Tao 1 , Zi-Shuo Yao 1
Affiliation  

A single crystal composed of one-dimensional coordinated polymers, [CdCl2(1-methyl-2-pyridone)]n, has been synthesized and characterized. This compound exhibits outstanding elastic bending due to the molecular spring nature of the CdCl2 coordination framework and weak intermolecular interactions between the coordination chains. Owing to the helical arrangement of organic ligands surrounding the coordination structure, the compound crystallizes in a chiral space group. As a result, it displays compelling circular dichroism spectra and second harmonic generation properties.

中文翻译:

由一维手性配位聚合物组成的弹性单晶

合成并表征了由一维配位聚合物组成的单晶[CdCl 2 (1-甲基-2-吡啶酮)] n 。由于CdCl 2配位框架的分子弹性性质和配位链之间较弱的分子间相互作用,该化合物表现出出色的弹性弯曲。由于配位结构周围有机配体的螺旋排列,该化合物在手性空间群中结晶。因此,它显示出引人注目的圆二色光谱和二次谐波生成特性。
更新日期:2024-05-17
down
wechat
bug