Skip to content
Licensed Unlicensed Requires Authentication Published online by De Gruyter April 4, 2024

Experimental research of paraffin deposition with flow loops

  • Chang Hong Gao EMAIL logo

Abstract

Wax/paraffin deposition in production wells and oil pipelines is a major challenge for oil production. Extensive research has been conducted to improve understanding of this process. This paper presents a review of experimental work carried out with flow loops. Previous research investigated paraffin deposition process under the influences of temperature, flow rate/velocity, shear stress, water fraction, gas phase, pipe material, asphaltene concentration, and chemical inhibitors. Test results reveal that temperature and shear stress have significant impacts on wax deposition. Limited research has been conducted on wax deposition under multiphase flow. Even though more than 20 years of efforts have been spent on wax deposition studies, unfortunately we have not fully understood this phenomenon.


Corresponding author: Chang Hong Gao, School of Mining and Geosciences, Nazarbayev University, Astana 010000, Kazakhstan, E-mail:

  1. Research ethics: Not applicable.

  2. Author contributions: The author has accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The author states no conflict of interest.

  4. Research funding: None declared.

  5. Data availability: Not applicable.

References

Adeyanju, O.A., Oyekunle, L.O. (2019). Experimental study of water-in-oil emulsion flow on wax deposition in subsea pipelines, J. Pet. Sci. Eng. 182: 106294: 1-7, https://doi.org/10.1016/j.petrol.2019.106294.Search in Google Scholar

Aiyejina, A., Chakrabarti, D., Pilgrim, A., and Sastry, M. (2011). Wax formation in oil pipelines: a critical review. Int. J. Multiphase Flow 37: 671–694, https://doi.org/10.1016/j.ijmultiphaseflow.2011.02.007.Search in Google Scholar

Alhejaili, A., Bell, E., and Daraboina, N. (2023). Paraffin deposition in production lines: effect of operating parameters on deposition characteristics. Energy Fuels 37: 18642–18651, https://doi.org/10.1021/acs.energyfuels.3c03282.Search in Google Scholar

Apte, M., Matzain, A., Zhan, G.H., and Brill, J. (2001). Investigation of paraffin deposition during multiphase flow in pipelines and wellbores Part 2: modeling. J. Energy Resour. Technol. 123: 150–157.10.1115/1.1369359Search in Google Scholar

Bell, E., Lu, Y., Daraboina, N., and Saraca, C. (2021). Experimental investigation of active heating in removal of wax deposits. J. Pet. Sci. Eng. 200: 1–10, https://doi.org/10.1016/j.petrol.2021.108346.Search in Google Scholar

Bi, Q., Huang, Q., and Fan, K. (2016). Wax deposition laws of crude oil and radial differences of deposit properties. Oil Gas Storage Trans. 36: 1–6.Search in Google Scholar

Bidmus, H.O. and Mehrotra, A.K. (2009). Solids deposition during cold flow of wax-solvent mixtures in a flow-loop apparatus with heat transfer. Energy Fuels 23: 3184–3194, https://doi.org/10.1021/ef900224r.Search in Google Scholar

Brill, J. and Mukherjee, H. (1999). Multiphase flow in wells. Society of Petroleum Engineers, Richardson Texas.Search in Google Scholar

Chi, Y., Daraboina, N., and Sarica, C. (2017). Effect of the flow field on the wax deposition and performance of wax inhibitors: cold finger and flow loop testing. Energy Fuels 31: 4915–4924, https://doi.org/10.1021/acs.energyfuels.7b00253.Search in Google Scholar

Chi, Y., Sarica, C., and Daraboina, N. (2019). Experimental investigation of two-phase gas-oil stratified flow wax deposition in pipeline. Fuel 247: 113–125, https://doi.org/10.1016/j.fuel.2019.03.032.Search in Google Scholar

Duan, J., Deng, S., Xu, S., Liu, H., Chen, M., and Gong, J. (2018). The effect of gas flow rate on the wax deposition in oil-gas stratified pipe flow. J. Pet. Sci. Eng. 162: 539–547, https://doi.org/10.1016/j.petrol.2017.10.058.Search in Google Scholar

Fan, K., Li, S., and Li, W. (2022a). Experimental study on the wax deposit properties in the crude oil pipeline. Pet. Sci. Technol. 40: 2737–2754, https://doi.org/10.1080/10916466.2022.2047067.Search in Google Scholar

Fan, K., Li, S., and Li, W. (2022b). Experimental study on the wax deposit properties in the radial direction in crude oil pipeline: wax precipitation, carbon number distribution. Pet. Sci. Technol. 40: 2319–2335, https://doi.org/10.1080/10916466.2022.2041663.Search in Google Scholar

Gao, C.H. (2003). Investigation of long term paraffin deposition behavior for South Pelto oil, M.Sc. Thesis. Tulsa, The University of Tulsa.Search in Google Scholar

Gao, C.H. (2018). Petroleum production technology. Science Press, Beijing.Search in Google Scholar

Geest, C., Guersoni, V., Garcia, D., and Bannwart, A. (2018). Wax deposition experiment with highly paraffinic crude oil in laminar single-phase flow unpredictable by molecular diffusion mechanism. Energy Fuels 32: 3406–3419, https://doi.org/10.1021/acs.energyfuels.8b00269.Search in Google Scholar

Gheriany, I. and Hassan, I. (2020) Proceeding of second novel intelligent and leading emerging sciences conference: a flow loop to study wax deposition in pipeline, Abuja Nigeria, pp. 532–537.Search in Google Scholar

Gong, J., Zhang, Y., Liao, L., Duan, J., Wang, P., and Zhou, J. (2011). Wax deposition in the oil gas two-phase flow for a horizontal pipe. Energy Fuels 25: 1624–1632, https://doi.org/10.1021/ef101682u.Search in Google Scholar

Haj-Shafiei, S. and Mehrotra, A.K. (2019). Achieving cold flow conditions for waxy mixtures with minimum solid deposition. Fuel 235: 1092–1099, https://doi.org/10.1016/j.fuel.2018.08.102.Search in Google Scholar

Hoffmann, R. and Amundsen, L. (2013). Influence of wax inhibitor on fluid and deposit properties. J. Pet. Sci. Eng. 107: 12–17, https://doi.org/10.1016/j.petrol.2013.04.009.Search in Google Scholar

Hoffmann, R., Amundsen, L., Huang, Z., Zheng, S., and Fogler, H.S. (2012). Wax deposition in stratified oil/water flow. Energy Fuels 26: 3416–3423, https://doi.org/10.1021/ef2018989.Search in Google Scholar

Huang, Q., Wu, H., and Zhang, J. (2000). A study of paraffin deposition with Xinjiang oil samples. Oil Gas Storage Trans. 19: 29–32.Search in Google Scholar

Huang, Q., Zhang, J., and Gao, X. (2006). Study on wax deposition of Daqing crude oil. Acta Petrol. Sin. 27: 125–129.Search in Google Scholar

Huang, Q., Zhao, C., and Chen, W. (2005). A new method for wax precipitation measurement. Oil Gas Storage Trans. 24: 34–38.Search in Google Scholar

Huang, Z., Lu, Y., Hoffmann, R., Amundsen, L., and Fogler, H.S. (2011). The effect of operating temperatures on wax deposition. Energy Fuels 25: 5180–5188, https://doi.org/10.1021/ef201048w.Search in Google Scholar

Ilushin, P., Vyatkin, K., and Kozlov, A. (2023). Development of a new model for the formation of wax deposits through the passage of crude oil within the well. Sustainability 15: 9616, https://doi.org/10.3390/su15129616.Search in Google Scholar

Ilyushin, P., Vyatkin, K., and Kozlov, A. (2022). Investigation of rheological properties of oil during the formation of wax deposits. Results Eng. 14: 100434, https://doi.org/10.1016/j.rineng.2022.100434.Search in Google Scholar

Janamatti, A., Lu, Y., and Ravichandran, S. (2019). Influence of operating temperatures on long-duration wax deposition in flow lines. J. Pet. Sci. Eng. 183, https://doi.org/10.1016/j.petrol.2019.106373.Search in Google Scholar

Kang, P., Hwang, J.Y., and Lim, J. (2019). Flow rate effect on wax deposition behavior in single-phase laminar flow. J. Energy Resour. Technol. 141: 032903, https://doi.org/10.1115/1.4041525.Search in Google Scholar

Karwa, R. (2017). Heat and mass transfer. Springer, Singapore.10.1007/978-981-10-1557-1Search in Google Scholar

Kasumu, A.S. and Mehrotra, A.K. (2013). Solids deposition from two-phase wax–solvent–water waxy mixtures under turbulent Flow. Energy Fuels 27: 1914–1925, https://doi.org/10.1021/ef301897d.Search in Google Scholar

Kilincer, N. (2003) Multiphase flow wax deposition behavior of Garden Banks condensate, M.Sc. Thesis. Tulsa, The University of Tulsa.Search in Google Scholar

Kriz, P. and Andersen, S. (2005). Effect of asphaltene on crude oil wax crystallization. Energy Fuels 29: 948–953, https://doi.org/10.1021/ef049819e.Search in Google Scholar

Lashkarbolooki, M., Seyfaee, A., Esmaeilzadeh, F., and Mowla, D. (2010). Experimental investigation of wax deposition in Kermanshah crude oil through a monitored flow loop apparatus. Energy Fuels 24: 1234–1241, https://doi.org/10.1021/ef9010687.Search in Google Scholar

Li, R., Huang, Q., Huo, F., Fan, K., Li, W., and Zhang, D. (2019). Effect of shear on the thickness of wax deposit under laminar flow regime. J. Pet. Sci. Eng. 181: 106212, https://doi.org/10.1016/j.petrol.2019.106212.Search in Google Scholar

Li, R., Huang, Q., Zhang, D., Zhu, X., Shan, J., and Li, Z. (2020). Investigation of thickness and wax content of wax deposits in polyethylene pipe using a flow loop. AIChE J. 67: e17077, https://doi.org/10.1002/aic.17077.Search in Google Scholar

Li, R., Huang, Q., Zhu, X., Zhang, D., Lv, Y., and Larson, R.G. (2021). Investigation of delayed formation of wax deposits in polyethylene pipe using a flow-loop. J. Pet. Sci. Eng. 196: 108104, https://doi.org/10.1016/j.petrol.2020.108104.Search in Google Scholar

Liu, Z., Li, Y., Wang, W., Song, G., Lu, Z., and Ning, Y. (2020). Wax and wax–hydrate deposition characteristics in single, two, and three-phase pipelines: a Review. Energy Fuels 34: 13350–13368, https://doi.org/10.1021/acs.energyfuels.0c02749.Search in Google Scholar

Makwashi, N., Akubo, S., Sarkodie, K., and Zhao, D. (2018). International conference on ethics in construction: engaging best practices during waxy crude oil production to prevent deposition in the subsea pipeline, November 2018 London.Search in Google Scholar

Mu, X., Huang, Q., and Zhang, J. (2003). Effect of pipe wall shear stress on paraffin deposition. Oil Gas Storage Trans. 22: 1–4.Search in Google Scholar

Nazar, S., Dabir, B., and Islam, M. (2005). Experimental and mathematical modeling of wax deposition and propagation in pipes transporting crude oil. Energy Sources 27: 185–207, https://doi.org/10.1080/00908310490448262.Search in Google Scholar

Oliveira, G., Mansur, C., Lucas, E., González, G., and de Souza, W.F. (2007). The effect of asphaltene, naphthenic acids, and polymeric inhibitors on the pour point of paraffin solutions. J. Dispersion Sci. Technol. 28: 349–356, https://doi.org/10.1080/01932690601107526.Search in Google Scholar

Panacharoensawad, E. and Sarica, C. (2013). Experimental study of single-phase and two-phase water-in-crude-oil dispersed flow wax deposition in a mini pilot-scale flow loop. Energy Fuels 27: 5036–5053, https://doi.org/10.1021/ef400275h.Search in Google Scholar

Piroozian, A., Hemmati, M., Ismail, I., Manan, M., Bayat, A.I., and Mohsin, R. (2016). Effect of emulsified water on the wax appearance temperature of water-in-waxy-crude-oil emulsions. Thermochim. Acta 637: 132–142, https://doi.org/10.1016/j.tca.2016.05.014.Search in Google Scholar

Quan, Q., Ran, W., Ruan, C., and Wang, S. (2019) Fourth international conference on energy science and engineering: experimental study on wax deposition of gas emulsion during intermitted flow, Xian, China.10.1088/1755-1315/242/2/022021Search in Google Scholar

Quan, Q., Wang, S., Sun, N., Wang, Y., Li, R., and Gong, J. (2020). Experimental study on wax deposition of gas-liquid under intermittent flow. Pet. Sci. Technol. 38: 331–337, https://doi.org/10.1080/10916466.2019.1705854.Search in Google Scholar

Quan, Q., Wang, W., Wang, P., Yang, J., Gao, G., Yang, L., and Gong, J. (2016). Effect of oil temperature on the wax deposition of crude oil with composition analysis. Braz. J. Chem. Eng. 33: 1055–1061, https://doi.org/10.1590/0104-6632.20160334s20150023.Search in Google Scholar

Ragunathan, T., Husin, H., Wood, C. (2020) Wax formation mechanisms wax chemical inhibitors and factors affecting chemical inhibition, Appl. Sci., 2020, 10, 479, https://doi.org/10.3390/app10020479.Search in Google Scholar

Salehi, R., Ehsani, M., and Behbahani, T. (2020). A new experimental and modeling investigation of wax precipitation in pipelines based on asphaltene content. Pet. Chem. 61: 631–639, https://doi.org/10.1134/s0965544121030051.Search in Google Scholar

Sarica, C. and Panacharoensawad, E. (2012). Review of paraffin deposition research under multiphase flow conditions. Energy Fuels 26: 3968–3978, https://doi.org/10.1021/ef300164q.Search in Google Scholar

Singh, P., Venkatesan, R., Fogler, H.S., and Nagarajan, N. (2000). Formation and aging of incipient thin film wax-oil gels. AIChE J. 46: 1059–1074, https://doi.org/10.1002/aic.690460517.Search in Google Scholar

Theyab, M. and Diaz, P. (2016). Experimental study of wax deposition in pipeline. Int. J. Smart Grid Clean Energy 5: 174–181, https://doi.org/10.12720/sgce.5.3.174-181.Search in Google Scholar

Tinsley, J., Jahnke, J., Dettman, H., and Prudhome, R. (2009). Waxy gels with asphaltene 1: characterization of precipitation, gelation, yield Stress, and morphology. Energy Fuels 23: 2056–2064, https://doi.org/10.1021/ef800636f.Search in Google Scholar

Tiwary, R. and Mehrotra, A.K. (2009). Deposition from wax−solvent mixtures under turbulent flow: effects of shear rate and time on deposit properties. Energy Fuels 23: 1299–1310, https://doi.org/10.1021/ef800591p.Search in Google Scholar

Veiga, H., Fleming, F., and Azevedo, L. (2017). Wax deposit thermal conductivity measurements under flowing conditions. Energy Fuels 31: 11532–11547, https://doi.org/10.1021/acs.energyfuels.7b01131.Search in Google Scholar

Wang, Z., Liu, Y., Li, J., Zhuge, X., and Zhang, L. (2016). Study on two-phase oil–water gelling deposition behavior in low-temperature transportation. Energy Fuels 30: 4570–4582, https://doi.org/10.1021/acs.energyfuels.6b00294.Search in Google Scholar

White, M., Pierce, K., and Archarya, T. (2018). A review of wax formation and mitigation technologies in petroleum industry. SPE Prod. Oper. 33: 476–485, https://doi.org/10.2118/189447-pa.Search in Google Scholar

Yang, J., Mi, R., and Quan, Q. (2015). Wax deposition for water-in-oil emulsion. Oil Gas Field Surf. Eng. 34: 11–14.Search in Google Scholar

Yu, X., Gao, Y., Cai, D., Yao, W., Zhou, Y., Su, Y., and Liu, K. (2021). Wax deposition law under a gas–liquid bubbly flow pattern. ACS Omega 6: 23015–23022, https://doi.org/10.1021/acsomega.0c04911.Search in Google Scholar PubMed PubMed Central

Zhang, G. and Liu, G. (2010). Study on the wax deposition of waxy crude in pipelines and its applications. J. Pet. Sci. Eng. 70: 1–9, https://doi.org/10.1016/j.petrol.2008.11.003.Search in Google Scholar

Zhang, G., Xing, X., Liu, G., and Zhang, S. (2006). Wax deposition tests with Qinghai crude oil. Oil Gas Storage Trans. 25: 22–25.Search in Google Scholar

Zhang, Y., Yu, D., Deng, T., and Wang, P. (2013). Wax deposition under gas-liquid intermittent flow. Oil Gas Storage Trans. 32: 381–384.Search in Google Scholar

Zheng, S. and Fogler, H.S. (2015). Fundamental investigation of wax diffusion characteristics in water-in-oil emulsion. Ind. Eng. Chem. Res. 54: 4420–4428, https://doi.org/10.1021/ie501955e.Search in Google Scholar

Zheng, S., Khrutphisit, T., and Fogler, H.S. (2017). Entrapment of water droplets in wax deposits from water-in-oil dispersion and its impact on deposit build-up. Energy Fuels 31: 340–350, https://doi.org/10.1021/acs.energyfuels.6b02450.Search in Google Scholar

Received: 2023-07-30
Accepted: 2024-02-14
Published Online: 2024-04-04

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 12.6.2024 from https://www.degruyter.com/document/doi/10.1515/revce-2023-0041/html
Scroll to top button