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Director Deformations, Geometric Frustration, and Modulated Phases in Liquid Crystals
Annual Review of Condensed Matter Physics ( IF 22.6 ) Pub Date : 2022-03-10 , DOI: 10.1146/annurev-conmatphys-031620-105712
Jonathan V. Selinger 1
Affiliation  

This article analyzes modulated phases in liquid crystals, from the long-established cholesteric and blue phases to the recently discovered twist-bend, splay-bend, and splay nematic phases, as well as the twist-grain-boundary (TGB) and helical nanofilament variations on smectic phases. The analysis uses the concept of four fundamental modes of director deformation: twist, bend, splay, and a fourth mode related to saddle-splay. Each mode is coupled to a specific type of molecular order: chirality, polarization perpendicular and parallel to the director, and octupolar order. When the liquid crystal develops one type of spontaneous order, the ideal local structure becomes nonuniform, with the corresponding director deformation. In general, the ideal local structure is frustrated; it cannot fill space. As a result, the liquid crystal must form a complex global phase, which may have a combination of deformation modes, and may have a periodic array of defects. Thus, the concept of an ideal local structure under geometric frustration provides a unified framework to understand the wide variety of modulated phases.

中文翻译:


液晶中的变形、几何挫折和调制相的导向器

本文分析了液晶中的调制相,从长期确立的胆甾相和蓝相到最近发现的扭曲弯曲、斜向弯曲和斜向向列相,以及扭曲晶界 (TGB) 和螺旋纳米丝近晶相的变化。该分析使用导向器变形的四种基本模式的概念:扭曲、弯曲、张开和与鞍张开相关的第四种模式。每种模式都与特定类型的分子顺序耦合:手性、垂直和平行于导向器的偏振以及八极顺序。当液晶发展出一种自发有序时,理想的局部结构变得不均匀,相应的指向矢变形。一般来说,理想的局部结构受挫;它不能填满空间。因此,液晶必须形成一个复杂的全局相,它可能具有多种变形模式,并且可能具有周期性排列的缺陷。因此,几何挫折下的理想局部结构的概念提供了一个统一的框架来理解各种调制相位。

更新日期:2022-03-10
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